|
|
ent-copalyl_diphosphate <=> diphosphate + ent-kaurene
|
4.2.3.19
ent-kaurene synthase
5.5.1.13
ent-copalyl diphosphate synthase
|
–
–
|
MK
|
| |
BRENDA:
BR44342;
BS323512;
BS444312
KEGG:
R05092
MetaCyc:
4.2.3.19-RXN
|
|
|
|
geranylgeranyl_diphosphate <=> ent-kaurene + diphosphate
|
4.2.3.19
ent-kaurene synthase
|
–
|
M
|
| |
BRENDA:
BS392057
MetaCyc:
RXN-11778
|
|
|
|
ent-kaurene <=> Aconitine
|
not assigned
|
–
|
K
|
| |
KEGG:
R06195
|
|
|
|
ent-kaurene <=> Veatchine
|
not assigned
|
–
|
K
|
| |
KEGG:
R06196
|
|
|
|
ent-kaurene <=> stevioside
|
not assigned
|
–
|
K
|
| |
KEGG:
R08401
|
|
|
|
ent-kaurene + O2 + reduced_[NADPH-hemoprotein_reductase] <=> ent-kaur-16-en-19-ol + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.13.78
ent-kaurene oxidase
|
–
|
M
|
| |
MetaCyc:
1.14.13.78-RXN
|
|
|
|
ent-kaurene + H+ + NADPH + O2 <=> kauralexin_A1 + H2O + NADP+
|
1.14.13
|
–
|
M
|
| |
MetaCyc:
RXN-12599
|
|
|
|
ent-kaurene + O2 + reduced_[NADPH-hemoprotein_reductase] <=> ent-kaur-16-en-19-oate + H2O + oxidized_[NADPH-hemoprotein_reductase] + H+
|
1.14.14.86
ent-kaurene monooxygenase
|
–
|
|
| |
MetaCyc:
RXN-13190
|
|
|
|
ent-8alpha-hydroxylabd-13-en-15-yl_diphosphate <=> ent-13-epi-manoyl_oxide + ent-kaurene + diphosphate
|
4.2.3.19
ent-kaurene synthase
|
–
|
|
| |
BRENDA:
BS444851
|
|
|
|
ent-kaurene + reduced_flavodoxin + O2 <=> 3alpha-hydroxy-ent-kaurene + flavin + H2O
|
1.14.14.70
ent-sandaracopimaradiene 3-hydroxylase
|
–
|
|
| |
BRENDA:
BS429252
|
|
|
|
ent-copalyl_diphosphate <=> 16alpha-hydroxykaurane + ent-kaurene + diphosphate
|
4.2.3.19
ent-kaurene synthase
|
–
|
|
| |
BRENDA:
BS444305
|
|
|
|
ent-copalyl_diphosphate <=> ent-beyerene + ent-kaurene + diphosphate
|
4.2.3.19
ent-kaurene synthase
|
–
|
|
| |
BRENDA:
BS444307
|
|
|
|
copalyl_diphosphate <=> ent-16-alpha-hydroxy-kaurene + ent-kaurene
|
5.5.1.13
ent-copalyl diphosphate synthase
|
–
|
|
| |
BRENDA:
BS391688
|
|
|
|
geranylgeranyl_diphosphate <=> ent-kaurene
|
5.5.1.13
ent-copalyl diphosphate synthase
|
–
|
|
| |
BRENDA:
BS323513
|
|
